聚硫堇/金纳米粒子/还原型氧化石墨烯修饰电极测定过氧化氢

doi:10.3969/j.issn.2095-2198.2023.02.001

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详细阐述了聚硫堇/金纳米粒子/还原型氧化石墨烯修饰玻碳电极(PTh/AuNPs/rGO/GCE)为基础的电流型传感器的制备及其在过氧化氢检测中的应用.首先，以石墨粉为原料制备氧化石墨烯，通过扫描电子显微镜、紫外-可见吸收光谱、红外光谱对氧化石墨烯的形貌和结构进行表征.其次，利用电还原方法制备还原型氧化石墨烯/玻碳电极（rGO/GCE）.在氯金酸溶液中，rGO/GCE通过电还原方法得到相应的金纳米粒子修饰的rGO/GCE（AuNPs/rGO/GCE）.最后，采用电聚合方法将硫堇(Th)聚合到电极表面制备对过氧化氢有响应性的PTh/AuNPs/rGO/GCE电化学传感器.该传感器对过氧化氢表现出良好的选择性和响应性，检测过氧化氢浓度的线性范围为4~80 mmol/L，检出限低至0.1 mmol/L.该研究为过氧化氢的简单快速分析提供了新思路.

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石墨烯硫堇过氧化氢电化学金纳米粒子

Abstract:

The fabrication of a sensor based on polythionine(PTh)/gold nanoparticles(AuNPs)/reduced graphene oxide(rGO) composite modified glassy carbon electrode (PTh/AuNPs/rGO/GCE) and its application in the detection of H2O2 were described in details.Graphene oxide(GO) was first prepared from graphite powder,which was fully characterized by scanning electron microscopy,UV-Vis spectroscopy and infrared spectroscopy.Secondly,reduced graphite oxide/glassy carbon electrode (rGO/GCE) was prepared by electroreduction.In chloroauric acid solution,the corresponding gold nanoparticles modified rGO/GCE (AuNPs/rGO/GCE) was obtained by electroreduction of rGO/GCE.Finally,a PTh/AuNPs/rGO electrochemical sensor responsive to H2O2 was prepared using thionine(Th) as a functional monomer.The electrochemical behavior of H2O2 on the modified electrode PTh/AuNPs/rGO/GCE was investigated by cyclic voltammetry.Under the optimized conditions,the linear range for the detection of H2O2 concentration was 4-80 mmol/L and the detection limit was 01 mmol/L.This study provides a new idea for the simple and rapid analysis of H2O2.

Key words: graphene')" href="#">

graphene thionine hydrogen peroxide electrochemistry gold nanoparticles

出版日期: 2023-04-29 发布日期: 2024-06-06 整期出版日期: 2023-04-29

ZTFLH:

O657.14

基金资助:

辽宁省自然科学基金项目（2019-ZD-0086）；辽宁省教育厅项目（LJ2020009）；沈阳化工大学青年育苗项目（XXLQ2019004）；国家自然科学基金面上项目（21674066）

引用本文:

韩双, 张蔓琳, 杨金栾, 张璇, 张楠, 张志超.

聚硫堇/金纳米粒子/还原型氧化石墨烯修饰电极测定过氧化氢 [J]. 沈阳化工大学学报, 2023, 37(2): 97-103.
HAN Shuang, ZHANG Manlin, YANG Jinluan, ZHANG Xuan, ZHANG Nan, ZHANG Zhichao.

Determination of Hydrogen Peroxide on Polythionine/Gold Nanoparticles/Reduced Graphene Oxide Modified Electrode . Journal of Shenyang University of Chemical Technology, 2023, 37(2): 97-103.

链接本文:

https://xuebao.syuct.edu.cn/CN/10.3969/j.issn.2095-2198.2023.02.001 或 https://xuebao.syuct.edu.cn/CN/Y2023/V37/I2/97

［1］陈迪航,李绵庆.过氧化氢的应用领域与主要生产方法［J］.化工技术与开发,2011,40(3):32-35.

［2］王朋.过氧化氢消毒灭菌技术介绍［J］.医药工程设计,2012,33(6):46-48.

［3］吕伏建,李晓伟,徐雷金,等.双氧水协同光催化技术在工业污水处理中的应用［J］.染料与染色,2019,56(3):60-62.

［4］刘伟伟.新型双氧水漂白活化剂的研究［D］石家庄:河北科技大学,2010:12-13.

［5］陈加敏,孟家光,薛涛.双氧水漂白活化剂概述［J］.染整技术,2016,38(12):6-9,18.

［6］石晶,王金美,孟一娟,等.食品级过氧化氢及其在食品工业中的应用［J］.中国食品添加剂,2009,(4):62-64,45.

［7］陈超,陶倩,柳琦.食品级过氧化氢在食品工业中的应用［J］.食品研究与开发,2018,39(12):220-224.

［8］丁宇,杨磊,王晨光,等.食品级过氧化氢在细胞水平的毒理学研究［J］.食品研究与开发,2017,38(23):198-201.

［9］范荻,黄跃龙,刘建高,等.空气中过氧化氢残留降解的实验研究［J］.中国卫生检验杂志,2009,19(4)：937-938.

［10］陈媛,蔡云飞,余林翼.自动电位滴定仪测定过氧化氢含量的方法改进［J］.化工管理,2015(14):110-111.

［11］BANDI R,ALLE M,PARK C W,et al.Cellulose Nanofibrils/Carbon Dots Composite Nanopapers for the Smartphone-Based Colorimetric Detection of Hydrogen Peroxide and Glucose［J］.Sensors and Actuators B:Chemical,2021,330:129330.

［12］WANG J N,ZHOU Y J,ZENG M Q,et al.Zr(Ⅳ)-Based Metal-Organic Framework Nanocomposites with Enhanced Peroxidase Like Activity as a Colorimetric Sensing Platform for Sensitive Detection of Hydrogen Peroxide and Phenol［J］.Environmental Research,2022,203:111818.

［13］DONG W F,HUANG Y M.CeO2/C Nanowire Derived from a Cerium(Ⅲ) Based Organic Framework as a Peroxidase Mimic for Colorimetric Sensing of Hydrogen Peroxide and for Enzymatic Sensing of Glucose［J］.Microchimica Acta,2019,187(1):11.

［14］REZENDE F,BRANDES R P,SCHRDER K.Detection of Hydrogen Peroxide with Fluorescent Dyes［J］.Antioxidants & Redox Signaling,2018,29(6):585-602.

［15］ZHENG D J,YANG Y S,ZHU H LRecent Progress in the Development of Small-Molecule Fluorescent Probes for the Detection of Hydrogen Peroxide［J］.TrAC-Trends in Analytical Chemistry,2019,118:625-651.

［16］ZAMBRANO G,NASTRI F,PAVONE V,et al.Use of an Artificial Miniaturized Enzyme in Hydrogen Peroxide Detection by Chemiluminescence［J］.Sensors,2020,20(13):3793.

［17］尉晗昱.化学修饰电极检测微污染水中的亚硝酸根和过氧化氢［D］杭州:浙江工商大学,2015:47-59.

［18］向忠,王宇航,吴金波,等.过氧化氢检测方法研究进展［J］.纺织学报,2020,41(10):197-204.

［19］HU Y,HOJAMBERDIEV M,GENG D S.Recent Advances in Enzyme-Free Electrochemical Hydrogen Peroxide Sensors Based on Carbon Hybrid Nanocomposites［J］.Journal of Materials Chemistry C,2021,9(22):6970-6990.

［20］HAN S,YUAN Y L,HU L Z,et al.Electrochemical Derivatization of Carbon Surface by Reduction of Diazonium Salts in Situ Generated from Nitro Precursors in Aqueous Solutions and Electrocatalytic Ability of the Modified Electrode Toward Hydrogen Peroxide［J］.Electrochemistry Communications,2010,12(12):1746-1748.

［21］张倩,付时雨,李海龙,等.一种快速测定过氧化氢浓度的方法［J］.光谱学与光谱分析,2014,34(3):767-770,776.

［22］LE V T,VASSEGHIAN Y,DRAGOI E N,et al.A Review on Graphene-Based Electrochemical Sensor for Mycotoxins Detection［J］.Food and Chemical Toxicology,2021,148:111931.

［23］YU H T,GUO W,LU X,et al.Reduced Graphene Oxide Nanocomposite Based Electrochemical Biosensors for Monitoring Foodborne Pathogenic Bacteria:A Review［J］.Food Control,2021,127:108117.

［24］LIPI〖DD(-*8/9〗′〖DD)〗SKA W,GROCHOWSKA K,SIUZDAK K.Enzyme Immobilization on Gold Nanoparticles for Electrochemical Glucose Biosensors［J］.Nanomaterials,2021,11(5):1156.

［25］IRIARTE-MESA C,LPEZ Y C,MATOS-PERALTA Y,et al.Gold,Silver and Iron Oxide Nanoparticles:Synthesis and Bionanoconjugation Strategies Aimed at Electrochemical Applications［J］.Topics in Current Chemistry,2020,378(1):12.

［26］李巍.基于纳米金/硫堇修饰金电极的ABA安培免疫传感器的研制［D］长沙:湖南农业大学,2008:15-17.

［27］孔泳,穆绍林.硫堇的电化学聚合及聚硫堇的性质［J］.物理化学学报,2001,17(4):295-299.

［28］赵影.聚硫堇/氧化石墨烯光电极的制备及其在分析化学中的应用研究［D］青岛:青岛科技大学,2014:16-17.

［29］冯辉.基于聚硫堇与纳米复合材料的电化学生物传感器的研究［D］长沙:湖南大学,2006:10-11.

［30］GAN S Y,ZHONG L J,HAN D X,et al.Probing Bio-Nano Interactions between Blood Proteins and Monolayer-Stabilized Graphene Sheets［J］.Small,2015,11(43):5814-5825.

［31］张旭强,田彬,李振,等.石墨烯层状材料的拓扑结构与性能［J］.化学研究与应用,2017,29(12):1769-1777.

［32］YANG S,YUE W B,HUANG D Z,et al.A Facile Green Strategy for Rapid Reduction of Graphene Oxide by Metallic Zinc［J］.RSC Advances，2012,2(23):8827-8832.

［33］GAO Y,LI Y,ZHANG L,et al.Adsorption and Removal of Tetracycline Antibiotics from Aqueous Solution by Graphene Oxide［J］.Journal of Colloid and Interface Science,2012,368(1):540-546.

［34］SI Y C,SAMULSKI E T.Synthesis of Water Soluble Graphene［J］.Nano Letters,2008,8(6):1679-1682.

［35］刘吟秋,周康,陈雅娴,等.还原氧化石墨烯/聚(N-甲基硫堇)复合材料的电化学合成及其电化学性质［J］.当代化工,2018,47(12):2521-2525.

［36］石银涛,袁若,王娜,等.基于聚硫堇和纳米金固定辣根过氧化物酶的生物传感器［J］.西南师范大学学报(自然科学版),2006,31(3):80-84.

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