癸二胺,苯并噁嗪,丁腈橡胶,增强," /> 癸二胺,苯并噁嗪,丁腈橡胶,增强,"/> decanediamine,benzoxazine,acrylonitril-butadiene rubber,reinforcement,"/> <p class="MsoNormal"> 癸二胺型苯并噁嗪树脂改性丁腈橡胶
Please wait a minute...
沈阳化工大学学报, 2023, 37(2): 124-128    doi: 10.3969/j.issn.2095-2198.2023.02.005
  材料科学与工程 本期目录 | 过刊浏览 | 高级检索 |

癸二胺型苯并噁嗪树脂改性丁腈橡胶

(1. 沈阳化工大学 化学工程学院,辽宁 沈阳 110142

(2. .沈阳化工大学 材料科学与工程学院, 辽宁 沈阳 110142

(3. 辽宁省石油化工规划设计院有限公司, 辽宁 沈阳 110004

沈阳工业大学 材料科学与工程学院, 辽宁 沈阳 110870

Properties of Acrylonitril-Butadiene Rubber(NBR) Modified by Benzoxazine Resin

下载:  PDF (787KB) 
输出:  BibTeX | EndNote (RIS)      
摘要 

为提高丁腈橡胶的力学性能,采用共固化的方法制备癸二胺型苯并噁嗪树脂(Bz)改性的丙烯腈-丁二烯橡胶(NBR)复合材料NBR-Bz,着重研究NBR-Bz橡胶同未改性的NBR在机械性能方面的差异.研究结果表明:与完全用硫磺硫化的NBR相比,NBR-Bz橡胶的拉伸强度、断裂伸长率明显增加;添加5 gBz可以使拉伸强度增加68%,断裂伸长率增加66%.这说明癸二胺型苯并噁嗪树脂具有明显的增强和增韧作用.

服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
关键词:  癸二胺')" href="#">

癸二胺  苯并噁嗪  丁腈橡胶  增强    

Abstract: 

To improve the mechanical properties of nitrile rubber,a co-curing method was used to prepare acrylonitrile butadiene rubber (NBR) composite material NBR-Bz modified with decanediamine benzoxazine resin (Bz).The difference in mechanical properties between NBR-Bz rubber and unmodified NBR were studied.The test results showed that the tensile strength and elongation at break of NBR-Bz rubber were significantly increased compared with unmodified NBR.The addition of 5 g Bz can increase the tensile strength by 68% and fracture elongation by 66%.This indicates that the decanediamine benzoxazine resin has a significant strengthening and toughening effect.

Key words:  decanediamine')" href="#">

decanediamine    benzoxazine    acrylonitril-butadiene rubber    reinforcement

               出版日期:  2023-04-29      发布日期:  2024-06-06      整期出版日期:  2023-04-29
ZTFLH: 

TQ332

 
基金资助: 

辽宁省教育厅项目(LJ2020007,LJ2019012

引用本文:    
张婷婷, 王趱, 黄丽, 蒋宁, 张文政.

癸二胺型苯并噁嗪树脂改性丁腈橡胶 [J]. 沈阳化工大学学报, 2023, 37(2): 124-128.
ZHANG Tingting, WANG Zan, HUANG Li, JIANG Ning, ZHANG Wenzheng.

Properties of Acrylonitril-Butadiene Rubber(NBR) Modified by Benzoxazine Resin . Journal of Shenyang University of Chemical Technology, 2023, 37(2): 124-128.

链接本文:  
https://xuebao.syuct.edu.cn/CN/10.3969/j.issn.2095-2198.2023.02.005  或          https://xuebao.syuct.edu.cn/CN/Y2023/V37/I2/124

1LORENZ H,STEINHAUSER D,KLUEPPEL M.Morphology and Micro-Mechanics of Filled Elastomer Blends:Impact on Dynamic Crack PropagationM//GRELLMANN WHEINRICH GKALISKE Met alFracture Mechanics and Statistical Mechanics of Reinforced Elastomeric BlendsBerlinSpringer,2013:81-128.

2SU J,LI C HPreparation and Properties of Ethylene Propylene Diene Rubber/SiO2/Carbon Nanotubes CompositesJ.Advanced Materials Research,2017,1142:201-205.

3]沈双双,王益庆,祝静,等.拉伸过程中橡胶交联网络结构变化研究[J.橡胶工业,2012,59(5):261-264.

4FROGLEY M D,RAVICH D,WAGNER H D.Mechanical Properties of Carbon Nanoparticle-Reinforced ElastomersJComposites Science and Technology,2003,63(11):1647-1654.

5GAUTHIER C,CHAZEAU L,PRASSE T,et al.Reinforcement Effect of Vapour Grown Carbon Nanofibres as Fillers in Rubbery MatricesJ.Composites Science and Technology,2005,65(2):335-343.

6]郝旭东.纳米粒子增强弹性体复合材料有限元分析及本构方程研究[D.北京:北京化工大学,2016:1-79.

7MOHAPATRA S,ALEX RNANDO G B.Cardanol Grafted Natural Rubber:A Green Substitute to Natural Rubber for Enhancing Silica Filler DispersionJ.Journal of Applied Polymer Science,2016133(8):43057.

[8GRUDD D T.Comments on Aaxial X-Ray Scattering on High Performance Polymeric Fibers”[J.Journal of Polymer Science Part B-Polymer Physics,1996,34(6):1159-1161.

9]向海,顾宜.新型酚醛树脂-苯并噁嗪树脂的研究进展[J.高分子材料科学与工程,2004,20(3):1-4,8.

10]顾宜,赵培,王智,等.苯并噁嗪树脂增韧改性研究进展[C//17届全国复合材料学术会议(复合材料及原材料分论坛)论文集.北京:中国宇航出版社,2012477-480.

11]刘欣,顾宜.苯并噁嗪热固化过程中体积变化的研究[J.高分子学报,2000(5):612-619.

[1] 刘徐越, 龙佳朋.

石墨烯/HDPE复合材料的制备及性能研究 [J]. 沈阳化工大学学报, 2023, 37(3): 233-238.

[2] 李大舟, 张小明, 高巍.

基于残差胶囊增强网络的手写化学方程式配平 [J]. 沈阳化工大学学报, 2023, 37(1): 87-96.

[3] 赵洋, 闵升锋, 李大舟.
基于主成分分析的轮胎缺陷检测算法研究
[J]. 沈阳化工大学学报, 2022, 36(2): 187-.
[4] 韩珩, 王照洲, 王伟志. 丁腈橡胶表面磺化改性及其在干摩擦条件下的摩擦学行为 [J]. 沈阳化工大学学报, 2022, 36(2): 128-133.
[5] 诗雨桐, 袁德成.

基于深度学习的面部微表情识别 [J]. 沈阳化工大学学报, 2021, 35(4): 380-384.

No Suggested Reading articles found!
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed